~30% natural rubber with the rest being synthetic polymers, woven fabrics, steel, stabilizers, and carbon black, silicates are also included to change the properties of the tire.
If you don't account for the structural components and just tread composition it's probably closer to 40%
The methane just breaks down into an equivalent amount of CO2 when vented anyways and until then is a much more potent greenhouse gas. That's why it's usually flared off apart from safety.