this post was submitted on 27 Jun 2025
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I agree that hydroxile hydride is the best, but the dihydro ether one is wrong. Ethers are defined by carbon bound to oxygen. No carbon bound to oxygen? No ether!
Hydroxyl hydride feels wrong given that hydride is H-. So what's a good name for HO+...? Oxenium hydride? Hydrenium hydride? (comparing carbonium (CR4H+) vs carbenium (CR3+) and oxonium/hydronium (H3O+))
Good point, maybe hydroxonium for OH+? I just know I never want to be in the same lab as a real OH+ species. Sounds like one of those "things I don't want to work with"
-onium is usually an extra group/proton (carbonium, oxonium, bromonium...). HO+ isn't too hard to approximate--just take a hydroperoxide or peroxyacid and add strong acid like with piranha :)